Rum is made from boiled sugarcane juice, the molasses, through a process of fermentation and distillation. Fermentation will result in the transformation of existing sugars in the juice into ethyl alcohol, that way the rum does not contain sugar.
It really depends on the type of rum. Rum on its own is sugar free. Rum is distilled so there usually isn't any reason for sugar to be added. Some processed or mixed versions of rum do contain sugar.
Even though rum is made out of by distilling sugarcane molasses or sugarcane juice, after the process of fermentation and distilling, its transformed in alcohol. Hence, the final product does not contain sugar.
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